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HMPA‐Promoted Siladifluoromethylation of Di‐, and Triarylmethanes with the Ruppert–Prakash Reagent
Author(s) -
Ji Xinfei,
Zhao Xianghu,
Shi Hongyan,
Cao Song
Publication year - 2017
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201701224
Subject(s) - reagent , chemistry , combinatorial chemistry , organic chemistry
A mild and efficientmethod for the synthesis of α‐siladifluoromethylated di‐, and triarylmethanes via the reaction of di‐, and triarylmethanes with Ruppert–Prakash reagents, using LDA and HMPA at room temperature, was developed.