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Synthesis, Optoelectronic and Self‐Assembly Properties of Diazadioxaacene Derivatives
Author(s) -
Pan Huahang,
Duan Jingdan,
Zhai Guixia,
Jin Pengcheng,
Zhao Xiaohui,
Jiang Li,
Xiao Jinchong
Publication year - 2017
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201700700
Subject(s) - pulmonary surfactant , fluorescence , topology (electrical circuits) , materials science , molecule , nanotechnology , nanowire , self assembly , simple (philosophy) , optoelectronics , combinatorial chemistry , chemical engineering , chemistry , organic chemistry , physics , optics , electrical engineering , engineering , philosophy , epistemology
Two novel diazadioxaacene derivatives ( ADOP and ADOQ ) have been successfully synthesized and characterized. Their single crystal analyses disclose that molecule ADOP forms a twisted topology configuration, whereas ADOQ adopts reclining‐chair architecture. Both of them emit strong blue fluorescence in organic solvents. Moreover, they can self‐assemble to form regular nanobelts and nanowires, respectively, via a simple surfactant‐assisted method.
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