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Synthesis and Structure of N , N ‐Dinitroamidoborane Complexes
Author(s) -
Shitov Oleg P.,
Tartakovsky Vladimir A.,
Golovanov Ivan S.,
Sukhorukov Alexey Yu.,
Ioffe Sema L.
Publication year - 2017
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201700603
Subject(s) - halide , borohydride , substitution (logic) , chemistry , stereochemistry , crystallography , organic chemistry , catalysis , computer science , programming language
A general approach to the synthesis of borohydride complexes containing one or two dinitroamide fragments has been suggested. Based on a smooth substitution of halide in haloborane or dibromoborane complexes with N , N ‐dinitroamide salts, this method provides various N , N ‐dinitroamidoboranes complexes in good yields and in analytically pure form. By means of spectroscopic and computational methods, it was demonstrated that dinitroamidoborane complexes could form as both B,N‐ and B,O‐isomers, which did not interconvert at ambient temperature.