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Amidoselenation and Amidotelluration of Alkenes using Oxygen as Terminal Oxidant
Author(s) -
Sun Kai,
Wang Xin,
Zhang Chong,
Zhang Saifei,
Chen Yao,
Jiao Hezhen,
Du Weimin
Publication year - 2017
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201700017
Subject(s) - derivatization , chemistry , substrate (aquarium) , functional group , tellurium , combinatorial chemistry , oxygen , reaction conditions , organic chemistry , catalysis , high performance liquid chromatography , oceanography , geology , polymer
A protocol has been established for oxygen‐mediated amidoselenation and amidotelluration of alkenes under mild conditions. This method provides a simple route to a series of structurally diverse β‐amido selenides and β‐amido tellurides in moderate to high yields. The wide substrate scope, good functional group tolerance, ease of large‐scale preparation and potential for product derivatization make this reaction attractive for the synthesis of nitrogen‐, selenium‐ and tellurium‐containing molecules.