6‐TIPS‐β‐Cyclodextrin‐Modified Fe 3 O 4  for Facile Enantioseparation of 1‐(1‐Naphthyl)ethylamine | Zendy

Wang Lu | Zendy; Liang XiangYong | Zendy; Ding LiSheng | Zendy; Zhang Sheng | Zendy; Li BangJing | Zendy

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6‐TIPS‐β‐Cyclodextrin‐Modified Fe 3 O 4 for Facile Enantioseparation of 1‐(1‐Naphthyl)ethylamine

Author(s) -

Wang Lu,

Liang XiangYong,

Ding LiSheng,

Zhang Sheng,

Li BangJing

Publication year - 2016

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201601151

Subject(s) - ethylamine , cyclodextrin , chemistry , combinatorial chemistry , chromatography , organic chemistry

A new type of chiral magnetic nanoparticle was prepared from covalently linked magnetic nanoparticles (Fe 3 O 4 ) and heptakis‐(6‐O‐triisopropylsilyl)‐β‐cyclodextrin (6‐TIPS‐β‐CD). The resulting selectors (TIPS‐β‐CD‐MNPs) combined the good magnetic properties Fe 3 O 4 and efficient chiral recognition ability of 6‐TIPS‐β‐CD. The enantioselectivity of TIPS‐β‐CD‐MNPs towards 1‐(1‐naphthyl)ethylamine was six times higher than that of the parent β‐CD modified Fe 3 O 4 particles.

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