Brønsted Acid‐Catalyzed Synthesis of  N ‐Arylindoles from 2‐Vinylanilines and Quinones | Zendy

Zhang HanMing | Zendy; Gao ZhongHua | Zendy; Yi Liang | Zendy; Ye Song | Zendy

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Brønsted Acid‐Catalyzed Synthesis of N ‐Arylindoles from 2‐Vinylanilines and Quinones

Author(s) -

Zhang HanMing,

Gao ZhongHua,

Yi Liang,

Ye Song

Publication year - 2016

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201600420

Subject(s) - intramolecular force , brønsted–lowry acid–base theory , electrophile , catalysis , chemistry , quinone , terminal (telecommunication) , medicinal chemistry , double bond , stereochemistry , organic chemistry , computer science , telecommunications

In the presence of a quinone, Brønsted acid‐catalyzed intramolecular C−N bond formation of o ‐vinylanilines by electrophilic cyclization was developed, giving the corresponding N ‐arylindoles in good to high yields. The reaction worked well for o ‐vinylanilines with terminal and internal C=C double bonds.

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