Synthesis, Isolation and Structure of Trifluoromethylated Fullerene  D  3 ‐C 78 , C 78 (1)(CF 3 ) 10−18 | Zendy

Kosaya Maria P. | Zendy; Fritz Maria A. | Zendy; Brotsman Victor A. | Zendy; Tamm Nadezhda B. | Zendy; Ignat'eva Daria V. | Zendy; Troyanov Sergey I. | Zendy

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Synthesis, Isolation and Structure of Trifluoromethylated Fullerene D 3 ‐C 78 , C 78 (1)(CF 3 ) 10−18

Author(s) -

Kosaya Maria P.,

Fritz Maria A.,

Brotsman Victor A.,

Tamm Nadezhda B.,

Ignat'eva Daria V.,

Troyanov Sergey I.

Publication year - 2016

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201600094

Subject(s) - trifluoromethylation , fullerene , chemistry , molecule , stereochemistry , organic chemistry , trifluoromethyl , alkyl

High‐temperature trifluoromethylation of fullerene C 78 followed by HPLC separation of C 78 (CF 3 ) n derivatives resulted in the isolation and X‐ray structural characterization of 15 compounds, that is, two C 78 (1)(CF 3 ) 10 , three C 78 (1)(CF 3 ) 12 , four C 78 (1)(CF 3 ) 14 , and five C 78 (1)(CF 3 ) 16 isomers as well as one isomer of C 78 (1)(CF 3 ) 18 . The addition patterns of the C 78 (1)(CF 3 ) n molecules are discussed in terms of trifluoromethylation pathways and relative formation energies.

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