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Möbius Aromatic Core‐Modified Heterocyclic [20] Macrocycles (4.1.1) with a Protruding N ‐Methyl Pyrrole Ring
Author(s) -
Mallick Abhijit,
Rath Harapriya
Publication year - 2016
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201600025
Subject(s) - pyrrole , moiety , regioselectivity , ring (chemistry) , chemistry , condensation , combinatorial chemistry , organic chemistry , catalysis , physics , thermodynamics
Herein, we report the first synthesis of an unorthodox tripyrrane moiety from the regioselective β‐benzoylation of pyrrole and the acid‐catalyzed condensation of the desired precursors. A [3+1] Mac Donald type condensation strategy for this tripyrrane has led to the exclusive isolation of two hitherto‐unknown aromatic [20] heterocyclic macrocycles (4.1.1).
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