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Inside Cover: Multicomponent One‐pot Reactions Towards the Synthesis of Stereoisomers of Dipicolylamine Complexes (Chem. Asian J. 1/2016)
Author(s) -
Raje Sakthi,
Gurusamy Sureshbabu,
Koner Abhishek,
Mehrotra Sonam,
Jennifer Samson Jegan,
Vasudev Prema G.,
Butcher Ray J.,
Angamuthu Raja
Publication year - 2016
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201501293
Subject(s) - chemistry , hemiaminal , ethylenediamine , stereoselectivity , covalent bond , pyridine , thiol , alcohol , transition metal , ligand (biochemistry) , ether , stereochemistry , medicinal chemistry , organic chemistry , polymer chemistry , catalysis , biochemistry , receptor
Stereoselective syntheses of dipicolylamine complexes of Zn, Cu, Ni, and Cd have been achieved by taking advantage of a four‐component dynamic covalent assembly comprising pyridine‐2‐carboxaldehyde, an N ‐substituted ethylenediamine, an aliphatic primary alcohol or thiol, and a transition‐metal ion. Zn and Cu selectively bind to the syn forms of the hemiaminal ether ligand whereas Ni and Cd selectively bind to the anti forms. More information can be found in the Full Paper by Raja Angamuthu et al. on page 128 in Issue 1, 2016 (DOI: 10.1002/asia.201500889).