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Reduced Graphene Oxide–Ag 3 PO 4 Heterostructure: A Direct Z‐Scheme Photocatalyst for Augmented Photoreactivity and Stability
Author(s) -
Samal Alaka,
Das D. P.,
Nanda K. K.,
Mishra B. K.,
Das J.,
Dash A.
Publication year - 2016
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201501286
Subject(s) - graphene , photocatalysis , visible spectrum , oxide , heterojunction , radical , mineralization (soil science) , photochemistry , materials science , chemistry , chemical engineering , nanotechnology , catalysis , optoelectronics , organic chemistry , nitrogen , engineering
A visible light driven, direct Z‐scheme reduced graphene oxide–Ag 3 PO 4 (RGO–Ag 3 PO 4 ) heterostructure was synthesized by means of a simple one‐pot photoreduction route by varying the amount of RGO under visible light illumination. The reduction of graphene oxide (GO) and growth of Ag 3 PO 4 took place simultaneously. The effect of the amount of RGO on the textural properties and photocatalytic activity of the heterostructure was investigated under visible light illumination. Furthermore, total organic carbon (TOC) analysis confirmed 97.1 % mineralization of organic dyes over RGO–Ag 3 PO 4 in just five minutes under visible‐light illumination. The use of different quenchers in the photomineralization suggested the presence of hydroxyl radicals ( . OH), superoxide radicals ( . O 2 − ), and holes (h + ), which play a significant role in the mineralization of organic dyes. In addition to that, clean hydrogen fuel generation was also observed with excellent reusability. The 4 RGO–Ag 3 PO 4 heterostructure has a high H 2 evolution rate of 3690 μmol h −1 g −1 , which is 6.15 times higher than that of RGO.