6,7‐Bismethoxy‐2,11‐dihydroxytetraphenylene Derived Macrocycles: Synthesis, Structures, and Complexation with Fullerenes | Zendy

Deng ChunLin | Zendy; Xiong XiaoDong | Zendy; Chik David T. W. | Zendy; Cai Zongwei | Zendy; Peng XiaoShui | Zendy; Wong Henry N. C. | Zendy

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6,7‐Bismethoxy‐2,11‐dihydroxytetraphenylene Derived Macrocycles: Synthesis, Structures, and Complexation with Fullerenes

Author(s) -

Deng ChunLin,

Xiong XiaoDong,

Chik David T. W.,

Cai Zongwei,

Peng XiaoShui,

Wong Henry N. C.

Publication year - 2015

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201500689

Subject(s) - fullerene , toluene , solid state , block (permutation group theory) , palladium , diffraction , chemistry , coupling (piping) , crystallography , materials science , computational chemistry , combinatorial chemistry , stereochemistry , catalysis , organic chemistry , mathematics , combinatorics , physics , optics , metallurgy

6,7‐Bismethoxy‐2,11‐dihydroxytetraphenylene ( 1 ), a novel building block of tetraphenylene‐derived macrocycles, was synthesized via palladium‐catalyzed cross‐coupling reactions and characterized by X‐ray diffraction. The relevant macrocyclic hosts derived from 1 have well‐defined structures with fixed conformations both in solution and solid state. They showed efficient and unique properties toward complexation with fullerenes C 60 and C 70 in toluene.

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