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Palladium‐Catalyzed One‐Pot Carbonylative Sonogashira Reaction Employing Formic acid as the CO Source
Author(s) -
Qi Xinxin,
Jiang LiBing,
Li ChongLiang,
Li Rui,
Wu XiaoFeng
Publication year - 2015
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201500518
Subject(s) - formic acid , palladium , sonogashira coupling , catalysis , aryl , chemistry , carbonylation , organic chemistry , combinatorial chemistry , carbon monoxide , alkyl
A convenient palladium‐catalyzed carbonylative coupling of aryl iodides and terminal alkynes with formic acid as the CO precursor has been developed. A variety of alkynones were obtained in good yields in a one‐pot manner for the first time.