Aromaticity Switching in Porphyrinoids | Zendy

Pawlicki Miłosz | Zendy; LatosGrażyński Lechosław | Zendy

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Aromaticity Switching in Porphyrinoids

Author(s) -

Pawlicki Miłosz,

LatosGrażyński Lechosław

Publication year - 2015

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201500170

Subject(s) - aromaticity , focus (optics) , construct (python library) , transformation (genetics) , chemistry , frame (networking) , nanotechnology , computer science , materials science , physics , molecule , organic chemistry , telecommunications , optics , biochemistry , gene , programming language

The aromaticity of porphyrinoids can be substantially altered by reversible modification of their original electronic structures. Well‐defined modulators can be used as a means to initiate these modifications, including redox processes, acid–base chemistry, and conformational phenomena. This Focus Review emphasizes the situation for which a single macrocyclic frame alternatively adopts diatropic and paratropic features and both situations are readily and mutually exchangeable. Eventually, such a porphyrinoid transformation can be explored as a suitable element to construct switchable optoelectronic materials.

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