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Mesoionic Carbene‐Gold(I) Catalyzed Bis‐Hydrohydrazination of Alkynes with Parent Hydrazine
Author(s) -
Tolentino Daniel R.,
Jin Liqun,
Melaimi Mohand,
Bertrand Guy
Publication year - 2015
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201403408
Subject(s) - mesoionic , carbene , hydrazine (antidepressant) , catalysis , cationic polymerization , chemistry , surface modification , chloride , combinatorial chemistry , medicinal chemistry , polymer chemistry , organic chemistry , chromatography
A novel synthetic route gives access to mesoionic carbene and cyclopropenylidene supported gold chloride complexes. The corresponding cationic MIC‐gold complex obtained by chloride abstraction allows for the first transition metal‐catalyzed functionalization of both nitrogens of parent hydrazine.