Premium
A Multifunctional 3D Chiral Porous Ferroelectric Metal–Organic Framework for Sensing Small Organic Molecules and Dye Uptake
Author(s) -
Cao LiHui,
Wei YongLi,
Ji Can,
Ma MingLi,
Zang ShuangQuan,
Mak Thomas C. W.
Publication year - 2014
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201402785
Subject(s) - ferroelectricity , metal organic framework , organic molecules , materials science , porosity , metal , small molecule , molecule , organic dye , nanotechnology , chemical engineering , organic chemistry , optoelectronics , chemistry , adsorption , composite material , dielectric , engineering , metallurgy , biochemistry
Abstract A flexible aromatic multicarboxylate ligand and Cd II ions assemble into a chiral multihelical porous metal–organic framework with second‐order nonlinear optical and ferroelectric properties. The obtained guest‐free form highly selectively senses small organic molecules and adsorbs large dye molecules.