De Novo Synthesis of Imidazoles by Visible‐Light‐Induced Photocatalytic Aerobic Oxidation/[3+2] Cycloaddition/Aromatization Cascade | Zendy

Deng QiaoHui | Zendy; Zou YouQuan | Zendy; Lu LiangQiu | Zendy; Tang ZiLong | Zendy; Chen JiaRong | Zendy; Xiao WenJing | Zendy

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De Novo Synthesis of Imidazoles by Visible‐Light‐Induced Photocatalytic Aerobic Oxidation/[3+2] Cycloaddition/Aromatization Cascade

Author(s) -

Deng QiaoHui,

Zou YouQuan,

Lu LiangQiu,

Tang ZiLong,

Chen JiaRong,

Xiao WenJing

Publication year - 2014

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201402443

Subject(s) - aromatization , cycloaddition , photocatalysis , visible spectrum , chemistry , photochemistry , cascade , combinatorial chemistry , catalysis , organic chemistry , materials science , optoelectronics , chromatography

A visible‐light‐induced photocatalytic aerobic oxidation/[3+2] cycloaddition/aromatization cascade between secondary amines and isocyanides has been successfully developed. The reaction provides a general and efficient access to diversely substituted imidazoles and imidazo[1,5‐ a ]quinoxalin‐4(5 H )‐ones in good yields under mild conditions.

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