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Aliphatic Amine Discrimination by Pentafluorophenyl Dibromo BODIPY
Author(s) -
Sekhar Adiki Raja,
Kaloo Masood Ayoub,
Sankar Jeyaraman
Publication year - 2014
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201402389
Subject(s) - bodipy , fluorescence , amine gas treating , reactivity (psychology) , chemistry , primary (astronomy) , tertiary amine , photochemistry , combinatorial chemistry , organic chemistry , medicine , physics , alternative medicine , pathology , quantum mechanics , astronomy
Two new fluorescent BODIPY dyes have been designed and synthesized. They dyes differ in their meso substituents, which have different electronic properties. Their selective reactivity towards an Ar‐S N 2 reaction has been explored as a potential basis for colorimetric and fluorescent discrimination of primary, secondary and tertiary aliphatic amines. This dual‐mode, instantaneous recognition event is unprecedented.