Homogeneous Oxidation of Water by Iron Complexes with Macrocyclic Ligands | Zendy

Zhang Biaobiao | Zendy; Li Fei | Zendy; Yu Fengshou | Zendy; Cui Honghua | Zendy; Zhou Xu | Zendy; Li Hua | Zendy; Wang Yong | Zendy; Sun Licheng | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Homogeneous Oxidation of Water by Iron Complexes with Macrocyclic Ligands

Author(s) -

Zhang Biaobiao,

Li Fei,

Yu Fengshou,

Cui Honghua,

Zhou Xu,

Li Hua,

Wang Yong,

Sun Licheng

Publication year - 2014

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201400066

Subject(s) - homogeneous , catalysis , aqueous solution , chemistry , ligand (biochemistry) , oxygen , catalytic oxidation , turnover number , combinatorial chemistry , water soluble , macrocyclic ligand , aqueous medium , polymer chemistry , organic chemistry , molecule , receptor , biochemistry , physics , thermodynamics

The activity of eleven separated iron complexes and nine in situ‐generated iron complexes towards catalytic water oxidation have been examined in aqueous solutions with Ce(NH 4 ) 2 (NO 3 ) 6 as the oxidant. Two iron complexes bearing tridentate and tetradentate macrocyclic ligands were found to be novel water oxidation catalysts. The one with tetradentate ligand exhibited a promising activity with a turnover number of 65 for oxygen evolution.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research