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Total Synthesis of the Putative Structure of Xylarinol B
Author(s) -
More Atul A.,
Ramana Chepuri V.
Publication year - 2014
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201301647
Subject(s) - cycloaddition , total synthesis , alkyne , skeleton (computer programming) , chemistry , stereochemistry , biology , organic chemistry , catalysis , anatomy
The total synthesis of the putative structure of xylarinol B is described and the need to revise its structure is demonstrated. The central benzoxepine skeleton was constructed by employing a cobalt‐mediated bimolecular [2+2+2] Reppe–Vollhardt alkyne cycloaddition reaction.
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