Phosphine‐Initiated Domino Reaction: A Convenient Method for the Preparation of Spirocyclopentanones | Zendy

Liang Ling | Zendy; Li Erqing | Zendy; Xie Peizhong | Zendy; Huang You | Zendy

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Phosphine‐Initiated Domino Reaction: A Convenient Method for the Preparation of Spirocyclopentanones

Author(s) -

Liang Ling,

Li Erqing,

Xie Peizhong,

Huang You

Publication year - 2014

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201301641

Subject(s) - phosphine , annulation , domino , cascade reaction , combinatorial chemistry , chemistry , domino effect , reaction conditions , protocol (science) , quaternary carbon , catalysis , computer science , organic chemistry , physics , medicine , alternative medicine , pathology , enantioselective synthesis , nuclear physics

An efficient synthetic approach has been developed for the construction of the spirocyclopentanone skeleton via a phosphine‐catalyzed [3+2] annulation reaction. With this novel and economical protocol, various quaternary carbon‐centered spirocyclopentanones could be readily obtained.

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