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Bridge‐Localized HOMO‐Binding Character of Divinylanthracene‐Bridged Dinuclear Ruthenium Carbonyl Complexes: Spectroscopic, Spectroelectrochemical, and Computational Studies
Author(s) -
Ou YaPing,
Zhang Jing,
Xu Meng,
Xia Jianlong,
Hartl František,
Yin Jun,
Yu GuangAo,
Liu Sheng Hua
Publication year - 2014
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201301544
Subject(s) - anthracene , density functional theory , chemistry , electron paramagnetic resonance , ruthenium , photochemistry , absorption spectroscopy , spectroscopy , infrared spectroscopy , ligand (biochemistry) , computational chemistry , crystallography , nuclear magnetic resonance , organic chemistry , biochemistry , physics , receptor , quantum mechanics , catalysis
The electronic properties of four divinylanthracene‐bridged diruthenium carbonyl complexes [{RuCl(CO)(PMe 3 ) 3 } 2 (μCHCHArCHCH)] (Ar=9,10‐anthracene ( 1 ), 1,5‐anthracene ( 2 ), 2,6‐anthracene ( 3 ), 1,8‐anthracene ( 4 )) obtained by molecular spectroscopic methods (IR, UV/Vis/near‐IR, and EPR spectroscopy) and DFT calculations are reported. IR spectroelectrochemical studies have revealed that these complexes are first oxidized at the noninnocent bridging ligand, which is in line with the very small ν (CO) wavenumber shift that accompanies this process and also supported by DFT calculations. Because of poor conjugation in complex 1 , except oxidized 1 + , the electronic absorption spectra of complexes 2 + , 3 + , and 4 + all display the characteristic near‐IR band envelopes that have been deconvoluted into three Gaussian sub‐bands. Two of the sub‐bands belong mainly to metal‐to‐ligand charge‐transfer (MLCT) transitions according to results from time‐dependent DFT calculations. EPR spectroscopy of chemically generated 1 + – 4 + proves largely ligand‐centered spin density, again in accordance with IR spectra and DFT calculations results.