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Critical Evaluation of Adsorption–Desorption Hysteresis of Heavy Metal Ions from Carbon Nanotubes: Influence of Wall Number and Surface Functionalization
Author(s) -
Li Jie,
Chen Changlun,
Zhang Shouwei,
Ren Xuemei,
Tan Xiaoli,
Wang Xiangke
Publication year - 2014
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201301475
Subject(s) - adsorption , desorption , surface modification , carbon nanotube , hysteresis , metal ions in aqueous solution , metal , ion , inorganic chemistry , materials science , electrolyte , chemical engineering , chemistry , nanotechnology , organic chemistry , metallurgy , electrode , physics , quantum mechanics , engineering
Single‐, double‐, and multi‐walled carbon nanotubes (SWCNTs, DWCNTs, and MWCNTs), and two oxidized MWCNTs with different oxygen contents (2.51 wt % and 3.5 wt %) were used to study the effect of the wall number and surface functionalization of CNTs on their adsorption capacity and adsorption–desorption hysteresis for heavy metal ions (Ni II , Cd II , and Pb II ). Metal ions adsorbed on CNTs could be desorbed by lowering the solution pH. Adsoprtion of heavy metal ions was not completely reversible when the supernatant was replaced with metal ion‐free electrolyte solution. With increasing wall number and amount of surface functional groups, CNTs had more surface defects and exhibited higher adsorption capacity and higher adsorption–desorption hysteresis index (HI) values. The coverage of heavy metal ions on the surface of CNTs, solution pH, and temperature affect the metal ion adsorption–desorption hysteresis. A possible shift in the adsorption mechanism from mainly irreversible to largely reversible processes may take place, as the amount of metal ions adsorbed on CNTs increases. Heavy metal ions may be irreversibly adsorbed on defect sites.