Ferroelectric Transition in the Inorganic Supramolecular Complex (Hg 6 P 4 )(CuCl 3 ) 2 | Zendy

Jiang XiaoMing | Zendy; Yan ZhiBo | Zendy; Liu Dan | Zendy; Wang JingXue | Zendy; Liu MeiFeng | Zendy; Guo GuoCong | Zendy; Jin BiaoBing | Zendy; Li XiaoGuang | Zendy; Liu JunMing | Zendy

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Ferroelectric Transition in the Inorganic Supramolecular Complex (Hg 6 P 4 )(CuCl 3 ) 2

Author(s) -

Jiang XiaoMing,

Yan ZhiBo,

Liu Dan,

Wang JingXue,

Liu MeiFeng,

Guo GuoCong,

Jin BiaoBing,

Li XiaoGuang,

Liu JunMing

Publication year - 2013

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201301040

Subject(s) - ferroelectricity , pyroelectricity , supramolecular chemistry , crystallite , materials science , ion , polarization (electrochemistry) , crystallography , nanotechnology , chemical physics , condensed matter physics , optoelectronics , crystal structure , chemistry , dielectric , physics , organic chemistry

In a state of disorder : An inorganic supramolecular complex, (Hg 6 P 4 )(CuCl 3 ) 2 , was prepared that undergoes a ferroelectric transition at about 37 K, and its spontaneous polarization was determined to be about 114 μC m −2 in the polycrystalline form using the high‐precision pyroelectric current method. Weak electrostatic supramolecular interactions in 1 lead to the dynamic disorder of ions and ferroelectric transition.

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