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N‐Heterocyclic‐Carbene‐Catalyzed One‐Pot Synthesis of Hydroxamic Esters
Author(s) -
Song Xiaoxiao,
Ni Qijian,
Grossmann André,
Enders Dieter
Publication year - 2013
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201300938
Subject(s) - benzoin , catalysis , carbene , chemistry , organic chemistry , redox , hydroxamic acid , umpolung , reaction conditions , medicinal chemistry , nucleophile
The honey pot : The NHC‐catalyzed reaction between nitrosobenzenes, aromatic/aliphatic aldehydes, and enals proceeded through an aza‐benzoin‐type reaction and an internal redox esterification to afford hydroxamic esters in good yields.