A New Organic Two‐Electron Oxidant: 9,10‐Diaryl‐9,10‐dihydroanthracene‐9,10‐bis(ylium) | Zendy

Ichikawa Junji | Zendy; Tanabe Hiroyuki | Zendy; Yoshida Suguru | Zendy; Kawai Takaharu | Zendy; Shinjo Masahiko | Zendy; Fujita Takeshi | Zendy

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A New Organic Two‐Electron Oxidant: 9,10‐Diaryl‐9,10‐dihydroanthracene‐9,10‐bis(ylium)

Author(s) -

Ichikawa Junji,

Tanabe Hiroyuki,

Yoshida Suguru,

Kawai Takaharu,

Shinjo Masahiko,

Fujita Takeshi

Publication year - 2013

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201300710

Subject(s) - dication , chemistry , electron , combinatorial chemistry , oxidative phosphorylation , anthraquinone , medicinal chemistry , photochemistry , computer science , molecule , organic chemistry , physics , quantum mechanics , biochemistry

Strong as an Ox : A dicationic compound with a 9,10‐dihydroanthracene skeleton has been produced from the corresponding 9,10‐dialkoxy‐9,10‐dihydroanthracene, which was readily prepared from anthraquinone. The dication functions as a powerful two‐electron oxidant, comparable to aminium cation radicals, and has been employed in oxidative processes such as the self‐coupling of anilines and naphthols, and oxidative deprotection of p ‐methoxybenzyl (PMB) ethers.

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