Synthesis of Allyl Allenes through Three‐Component  Cross‐Coupling Reaction  of  N‐ Tosylhydrazones, Terminal Alkynes, and Allyl Halides | Zendy

Ye Fei | Zendy; Hossain Mohammad Lokman | Zendy; Xu Yan | Zendy; Ma Xiaoshen | Zendy; Xiao Qing | Zendy; Zhang Yan | Zendy; Wang Jianbo | Zendy

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Synthesis of Allyl Allenes through Three‐Component Cross‐Coupling Reaction of N‐ Tosylhydrazones, Terminal Alkynes, and Allyl Halides

Author(s) -

Ye Fei,

Hossain Mohammad Lokman,

Xu Yan,

Ma Xiaoshen,

Xiao Qing,

Zhang Yan,

Wang Jianbo

Publication year - 2013

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201300340

Subject(s) - terminal (telecommunication) , component (thermodynamics) , chemistry , carbene , halide , medicinal chemistry , combinatorial chemistry , computer science , catalysis , organic chemistry , physics , computer network , thermodynamics

Three's a crowd : Tri‐ and tetrasubstituted allyl allenes can be easily accessed by this Cu I ‐catalyzed three‐component coupling reaction of N ‐tosylhydrazones, terminal alkynes, and allyl halides. The reaction proceeds through a mechanism involving copper carbene migratory insertion.

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