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Desulfonylation of Tosyl Amides through Catalytic Photoredox Cleavage of NS Bond Under Visible‐Light Irradiation
Author(s) -
Xuan Jun,
Li BinJie,
Feng ZhuJia,
Sun GuoDong,
Ma HuanHuan,
Yuan ZhiWei,
Chen JiaRong,
Lu LiangQiu,
Xiao WenJing
Publication year - 2013
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201300224
Subject(s) - tosyl , cleavage (geology) , scope (computer science) , visible spectrum , chemistry , substrate (aquarium) , catalysis , combinatorial chemistry , photochemistry , computer science , organic chemistry , materials science , biology , programming language , optoelectronics , fracture (geology) , composite material , ecology
All lit up: A novel and efficient desulfonylation method of tosyl amides has been developed by means of visible‐light‐promoted reductive cleavage of NS bonds. This method has a broad substrate scope, good functional group tolerance, and excellent yields.