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Organic and Organometallic Nanofibers Formed by Supramolecular Assembly of Diamond‐Shaped Macrocyclic Ligands and Pd II Complexes
Author(s) -
Kuritani Masumi,
Tashiro Shohei,
Shionoya Mitsuhiko
Publication year - 2013
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201300209
Subject(s) - supramolecular chemistry , alkyl , nanofiber , diamond , polymer chemistry , crystallography , chemistry , group 2 organometallic chemistry , materials science , organometallic chemistry , stereochemistry , nanotechnology , organic chemistry , crystal structure , molecule
Stacked rings : A diamond‐shaped macrocycle with two inward phenanthroline ligands and outward long alkyl chains, and its Pd II complex form organic and organometallic fibrous aggregates, respectively, as revealed by NMR, UV/Vis, AFM, and TEM measurements. The most likely structures are face‐to‐face stacked macrocycles, generating nanotubes.