Assembly of {Mn 2 (salen) 2 } 2+  Dimers by Cyclic V 4 O 12  4−  Clusters: A 3 D Compound with Open‐Framework Structure Exhibiting Slow Magnetization Relaxation | Zendy

Wang TingTing | Zendy; Bao SongSong | Zendy; Ren Min | Zendy; Cai ZhongSheng | Zendy; Zheng ZeHua | Zendy; Xu ZhongLi | Zendy; Zheng LiMin | Zendy

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Assembly of {Mn 2 (salen) 2 } 2+ Dimers by Cyclic V 4 O 12 4− Clusters: A 3 D Compound with Open‐Framework Structure Exhibiting Slow Magnetization Relaxation

Author(s) -

Wang TingTing,

Bao SongSong,

Ren Min,

Cai ZhongSheng,

Zheng ZeHua,

Xu ZhongLi,

Zheng LiMin

Publication year - 2013

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201300167

Subject(s) - crystallography , schiff base , covalent bond , magnetization , chemistry , manganese , materials science , physics , organic chemistry , quantum mechanics , magnetic field

Sit back and relax : The title compound [Mn 6 (salen) 6 (H 2 O)V 4 O 12 ](ClO 4 ) 2 ⋅7 H 2 O is the first example of a 3D coordination polymer with embedded out‐of‐plane Mn III Schiff base dimers, where the Mn 2 (salen) 2 2+ dimers are connected by the cyclic V 4 O 12 4− clusters through covalent bonds. Slow magnetization relaxation is observed at low temperature.

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