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Assembly of {Mn 2 (salen) 2 } 2+ Dimers by Cyclic V 4 O 12 4− Clusters: A 3 D Compound with Open‐Framework Structure Exhibiting Slow Magnetization Relaxation
Author(s) -
Wang TingTing,
Bao SongSong,
Ren Min,
Cai ZhongSheng,
Zheng ZeHua,
Xu ZhongLi,
Zheng LiMin
Publication year - 2013
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201300167
Subject(s) - crystallography , schiff base , covalent bond , magnetization , chemistry , manganese , materials science , physics , organic chemistry , quantum mechanics , magnetic field
Sit back and relax : The title compound [Mn 6 (salen) 6 (H 2 O)V 4 O 12 ](ClO 4 ) 2 ⋅7 H 2 O is the first example of a 3D coordination polymer with embedded out‐of‐plane Mn III Schiff base dimers, where the Mn 2 (salen) 2 2+ dimers are connected by the cyclic V 4 O 12 4− clusters through covalent bonds. Slow magnetization relaxation is observed at low temperature.