1,2‐Bis(ferrocenyl)‐Substituted Distibene and Dibismuthene: SbSb and BiBi Units as π Spacers between Two Ferrocenyl Units | Zendy

Sakagami Michiyasu | Zendy; Sasamori Takahiro | Zendy; Sakai Heisuke | Zendy; Furukawa Yukio | Zendy; Tokitoh Norihiro | Zendy

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1,2‐Bis(ferrocenyl)‐Substituted Distibene and Dibismuthene: SbSb and BiBi Units as π Spacers between Two Ferrocenyl Units

Author(s) -

Sakagami Michiyasu,

Sasamori Takahiro,

Sakai Heisuke,

Furukawa Yukio,

Tokitoh Norihiro

Publication year - 2013

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201201227

Subject(s) - electrochemistry , antimony , ferrocene , conjugated system , crystallography , chemistry , materials science , inorganic chemistry , organic chemistry , electrode , polymer

Pi in the sky : 1,2‐bis(ferrocenyl)distibene and 1,2‐bis(ferrocenyl)dibismuthene derivatives, where two bulky ferrocenyl units are bridged by a SbSb and BiBi π spacer, have been synthesized as a new family of novel d–π conjugated systems. Their molecular structures, spectroscopic behavior, and electrochemical properties reveal the SbSb and BiBi units to be effective π‐electron spacers.

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