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Copper‐Catalyzed Synthesis of α‐Hydroxy Phosphonates from H ‐Phosphonates and Alcohols or Ethers
Author(s) -
Zhao Zengxiang,
Xue Wanhua,
Gao Yuxing,
Tang Guo,
Zhao Yufen
Publication year - 2013
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201201062
Subject(s) - catalysis , alkyl , chemistry , organic chemistry , copper , phosphonate , combinatorial chemistry
Easy PC : α‐Hydroxy phosphonates were synthesized by copper/ tert ‐butyl hydroperoxide (TBHP)‐catalyzed oxidative addition reactions of H ‐phosphonates with alcohols or ethers. Diverse α‐hydroxy phosphonates were obtained from substituted benzyl alcohols or alkyl alcohols and alkyl ethers in moderate to good yields.