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Straightforward Iron‐Catalyzed Synthesis of Vinylboronates by the Hydroboration of Alkynes
Author(s) -
Haberberger Michael,
Enthaler Stephan
Publication year - 2013
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201200931
Subject(s) - hydroboration , variety (cybernetics) , catalysis , chemistry , service (business) , computer science , combinatorial chemistry , organic chemistry , business , marketing , artificial intelligence
An iron‐catalyzed hydroboration of alkynes to produce vinylboronates has been examined. With a straightforward system composed of iron carbonyls and pinacolborane, good to excellent yields and chemoselectivities were achieved for a variety of alkynes.