Formation of a Nitrogenase P‐cluster [Fe 8 S 7 ] Core via Reductive Fusion of Two All‐Ferric [Fe 4 S 4 ] Clusters | Zendy

Ohki Yasuhiro | Zendy; Tanifuji Kazuki | Zendy; Yamada Norihiro | Zendy; Cramer Roger E. | Zendy; Tatsumi Kazuyuki | Zendy

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Formation of a Nitrogenase P‐cluster [Fe 8 S 7 ] Core via Reductive Fusion of Two All‐Ferric [Fe 4 S 4 ] Clusters

Author(s) -

Ohki Yasuhiro,

Tanifuji Kazuki,

Yamada Norihiro,

Cramer Roger E.,

Tatsumi Kazuyuki

Publication year - 2012

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201200568

Subject(s) - nitrogenase , cluster (spacecraft) , fusion , core (optical fiber) , ferric , chemistry , crystallography , materials science , inorganic chemistry , computer science , nitrogen fixation , nitrogen , linguistics , philosophy , organic chemistry , composite material , programming language

How does your cluster grow? The nitrogenase P‐cluster [Fe 8 S 7 ] core has been assembled from the two all‐ferric [Fe 4 S 4 ] clusters via phosphine desulfurization. This finding suggests that reductive desulfurization from an [Fe 4 S 4 ] cluster can occur in the maturation process of the P‐cluster of nitrogenase.

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