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Active versus Passive Substituent Participation in the Auxiliary‐Mediated Asymmetric Synthesis of an Octahedral Metal Complex
Author(s) -
Chen LiangAn,
Ma Jiajia,
Celik Mehmet Ali,
Yu HongLang,
Cao Zexing,
Frenking Gernot,
Gong Lei,
Meggers Eric
Publication year - 2012
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201200532
Subject(s) - chirality (physics) , substituent , metal , octahedron , enantioselective synthesis , ruthenium , asymmetric carbon , chemistry , stereochemistry , crystallography , materials science , crystal structure , organic chemistry , catalysis , chiral symmetry , physics , optically active , quark , quantum mechanics , nambu–jona lasinio model
Ambiguous chirality transfer : A surprising reversal of chirality transfer from carbon to metal is reported in the asymmetric synthesis of a chiral ruthenium complex, affording the metal‐centered configuration Λ or Δ depending only on the chemical composition of the side chain of a chiral salicyloxazoline auxiliary.