Active  versus  Passive Substituent Participation in the Auxiliary‐Mediated  Asymmetric Synthesis  of an Octahedral Metal Complex | Zendy

Chen LiangAn | Zendy; Ma Jiajia | Zendy; Celik Mehmet Ali | Zendy; Yu HongLang | Zendy; Cao Zexing | Zendy; Frenking Gernot | Zendy; Gong Lei | Zendy; Meggers Eric | Zendy

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Active versus Passive Substituent Participation in the Auxiliary‐Mediated Asymmetric Synthesis of an Octahedral Metal Complex

Author(s) -

Chen LiangAn,

Ma Jiajia,

Celik Mehmet Ali,

Yu HongLang,

Cao Zexing,

Frenking Gernot,

Gong Lei,

Meggers Eric

Publication year - 2012

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201200532

Subject(s) - chirality (physics) , substituent , metal , octahedron , enantioselective synthesis , ruthenium , asymmetric carbon , chemistry , stereochemistry , crystallography , materials science , crystal structure , organic chemistry , catalysis , chiral symmetry , physics , optically active , quark , quantum mechanics , nambu–jona lasinio model

Ambiguous chirality transfer : A surprising reversal of chirality transfer from carbon to metal is reported in the asymmetric synthesis of a chiral ruthenium complex, affording the metal‐centered configuration Λ or Δ depending only on the chemical composition of the side chain of a chiral salicyloxazoline auxiliary.

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