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Total Synthesis of (±)‐Parvineostemonine
Author(s) -
Chen ZhiHua,
Tian JinMiao,
Chen ZhiMin,
Tu YongQiang
Publication year - 2012
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201200493
Subject(s) - stereoselectivity , total synthesis , computer science , information retrieval , content (measure theory) , stereochemistry , chemistry , organic chemistry , mathematics , catalysis , mathematical analysis
Short and sweet : The first total synthesis of (±)‐parvineostemonine was achieved from commercially available tropinone in 11 steps. The synthetic approach features a radical‐mediated 7 ‐exo‐ trig cyclization and a stereoselective carbonyl allylation/lactonization.
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