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Palladium‐Catalyzed Reductive Carbonylation of Aryl Bromides with Phosphinite Ligands
Author(s) -
Neumann Helfried,
Kadyrov Renat,
Wu XiaoFeng,
Beller Matthias
Publication year - 2012
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201200462
Subject(s) - phosphinite , carbonylation , aryl , palladium , catalysis , reductive elimination , chemistry , organic chemistry , combinatorial chemistry , carbon monoxide , alkyl
A palladium‐catalyzed reductive carbonylation of aryl bromides into the corresponding aryl aldehydes has been described using synthesis gas in the presence of phosphinite ligands. Several products have been synthesized in moderate to good yields (35–97 %) under mild reaction conditions.