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High‐Performance Lithium‐Ion Anodes with Hierarchically Assembled Single‐Crystal SnO 2 Nanoflake Spheres
Author(s) -
Liu Zhaoyang,
Bai Hongwei,
Sun Darren Delai
Publication year - 2012
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201200429
Subject(s) - materials science , anode , lithium (medication) , spheres , nanoscopic scale , ion , graphite , porosity , chemical engineering , nanotechnology , electrode , lithium ion battery , composite material , battery (electricity) , power (physics) , chemistry , organic chemistry , medicine , physics , astronomy , quantum mechanics , engineering , endocrinology
A large‐scale hierarchical assembly route is reported for the formation of SnO 2 on the nanoscale that contains rigid and robust spheres with irregular channels for rapid access of Li ions into the hierarchically structured interiors. Large volume changes during the process of Li insertion and extraction are accommodated by the SnO 2 nanoflake spheres’ internal porosity. The hierarchical SnO 2 nanoflake spheres exhibit good lithium storage properties with high capacity and long‐lasting performance when used as lithium‐ion anodes. A reversible capacity of 517 mA h g −1 , still greater than the theoretical capacity of graphite (372 mA h g −1 ), after 50 charge–discharge cycles is attained. Meanwhile, the synthesis process is simple, inexpensive, safe, and broadly applicable, providing new avenues for the rational engineering of electrode materials with enhanced conductivity and power.