Premium
Stepwise Construction of a Ag I 9 –Cu II 4 Heterometallic Cluster Incorporating Two Unusual Vertex‐Shared Trigonal‐Bipyramidal Silver Polyhedra
Author(s) -
Sun Di,
Zhang Liangliang,
Yan Zhihao,
Sun Daofeng
Publication year - 2012
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201200181
Subject(s) - polyhedron , trigonal bipyramidal molecular geometry , vertex (graph theory) , cluster (spacecraft) , crystallography , trigonal crystal system , pentagonal bipyramidal molecular geometry , chemistry , bipyramid , physics , combinatorics , crystal structure , mathematics , computer science , graph , programming language
One step at a time : A novel tridecanuclear Ag I 9 –Cu II 4 heterometallic cluster comprising four [Cu(phen) 2 ] 2+ units on the periphery and one interior [Ag 9 (mna) 8 ] 7− cluster was synthesized in a stepwise manner and characterized. The interior [Ag 9 (mna) 8 ] 7− cluster contains two unusual vertex‐shared trigonal‐bipyramidal silver polyhedra.