Stepwise Construction of a Ag I  9 –Cu II  4  Heterometallic Cluster Incorporating Two Unusual Vertex‐Shared Trigonal‐Bipyramidal Silver Polyhedra | Zendy

Sun Di | Zendy; Zhang Liangliang | Zendy; Yan Zhihao | Zendy; Sun Daofeng | Zendy

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Stepwise Construction of a Ag I 9 –Cu II 4 Heterometallic Cluster Incorporating Two Unusual Vertex‐Shared Trigonal‐Bipyramidal Silver Polyhedra

Author(s) -

Sun Di,

Zhang Liangliang,

Yan Zhihao,

Sun Daofeng

Publication year - 2012

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201200181

Subject(s) - polyhedron , trigonal bipyramidal molecular geometry , vertex (graph theory) , cluster (spacecraft) , crystallography , trigonal crystal system , pentagonal bipyramidal molecular geometry , chemistry , bipyramid , physics , combinatorics , crystal structure , mathematics , computer science , graph , programming language

One step at a time : A novel tridecanuclear Ag I 9 –Cu II 4 heterometallic cluster comprising four [Cu(phen) 2 ] 2+ units on the periphery and one interior [Ag 9 (mna) 8 ] 7− cluster was synthesized in a stepwise manner and characterized. The interior [Ag 9 (mna) 8 ] 7− cluster contains two unusual vertex‐shared trigonal‐bipyramidal silver polyhedra.

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