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Iodine(III)‐Promoted Intermolecular Diamination of Alkenes
Author(s) -
Souto José A.,
González Yolanda,
Iglesias Alvaro,
Zian Debora,
Lishchynskyi Anton,
Muñiz Kilian
Publication year - 2012
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201101025
Subject(s) - hypervalent molecule , iodine , vicinal , reagent , chemistry , intermolecular force , alkene , radical , combinatorial chemistry , organic chemistry , catalysis , molecule
A rapid and productive vicinal diamination of alkenes takes place in the presence of a hypervalent iodine(III) reagent and bissulfonimides as nitrogen sources. A total of more than 60 examples are presented. The reaction is characterized by its robustness and its wide substrate scope: it proceeds selectively with both terminal and internal alkenes and tolerates a range of functional groups.