Iodine(III)‐Promoted Intermolecular  Diamination of Alkenes | Zendy

Souto José A. | Zendy; González Yolanda | Zendy; Iglesias Alvaro | Zendy; Zian Debora | Zendy; Lishchynskyi Anton | Zendy; Muñiz Kilian | Zendy

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Iodine(III)‐Promoted Intermolecular Diamination of Alkenes

Author(s) -

Souto José A.,

González Yolanda,

Iglesias Alvaro,

Zian Debora,

Lishchynskyi Anton,

Muñiz Kilian

Publication year - 2012

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201101025

Subject(s) - hypervalent molecule , iodine , vicinal , reagent , chemistry , intermolecular force , alkene , radical , combinatorial chemistry , organic chemistry , catalysis , molecule

A rapid and productive vicinal diamination of alkenes takes place in the presence of a hypervalent iodine(III) reagent and bissulfonimides as nitrogen sources. A total of more than 60 examples are presented. The reaction is characterized by its robustness and its wide substrate scope: it proceeds selectively with both terminal and internal alkenes and tolerates a range of functional groups.

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