Premium
An Imidazolium‐Based Fluorescent Cyclophane for the Selective Recognition of Iodide
Author(s) -
Suresh Vangaru,
Ahmed Nisar,
Youn Il Seung,
Kim Kwang S.
Publication year - 2012
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201100941
Subject(s) - cyclophane , fluorescence , iodide , titration , chemistry , fluorescence spectroscopy , combinatorial chemistry , computer science , organic chemistry , molecule , optics , physics
For your I's only : A new imidazolium‐based fluorescent cyclophane 1 was designed and synthesized that was quenched selectively in the presence of iodide but not other anions, as assessed by fluorimetry. In addition, fluorescence titration experiments, 1 H NMR spectroscopic data, and theoretical calculations provide evidence that 1 encapsulates two iodides inside its cavity.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom