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Palladium‐Catalyzed Carbonylative Dimerization of Styrenes to 1,5‐Diarylpent‐1‐en‐3‐ones
Author(s) -
Wu XiaoFeng,
Neumann Helfried,
Beller Matthias
Publication year - 2012
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201100836
Subject(s) - palladium , propane , catalysis , chemistry , scheme (mathematics) , computer science , organic chemistry , combinatorial chemistry , mathematics , mathematical analysis
A general palladium‐catalyzed carbonylative dimerization of styrenes has been developed. Starting from commercial available styrenes, symmetrical 1,5‐diarylpent‐1‐en‐3‐ones were produced in good to excellent yields (see scheme; dppp=1,3‐bis(diphenylphosphino)propane).