Air‐Stable, Narrow‐Band‐Gap Ambipolar C 60  Fullerene–Hydrazone  Hybrid Materials | Zendy

Urnikaite Simona | Zendy; Malinauskas Tadas | Zendy; Gaidelis Valentas | Zendy; Jankauskas Vygintas | Zendy; Getautis Vytautas | Zendy

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Air‐Stable, Narrow‐Band‐Gap Ambipolar C 60 Fullerene–Hydrazone Hybrid Materials

Author(s) -

Urnikaite Simona,

Malinauskas Tadas,

Gaidelis Valentas,

Jankauskas Vygintas,

Getautis Vytautas

Publication year - 2012

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201100781

Subject(s) - ambipolar diffusion , hydrazone , fullerene , cyclic voltammetry , band gap , materials science , ionization , ionization energy , analytical chemistry (journal) , electron , photochemistry , optoelectronics , chemistry , electrode , electrochemistry , organic chemistry , ion , physics , quantum mechanics

Fullerene–hydrazone dyads have been synthesized using the Confalone reaction followed by condensation with phenylhydrazines. Room‐temperature xerographic time‐of‐flight, ionization potential, and cyclic voltammetry measurements indicate that these narrow‐band‐gap ( E g <1.5 eV), ambipolar charge‐transporting dyads with balanced hole‐ and electron mobilities, which operate in air, are attractive materials for various optoelectronic applications.

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