Metal‐Crossing between Thiolato‐Bridged Tetragold(I) and Tetrasilver(I) Metallorings | Zendy

Takino Yusuke | Zendy; Tsuge Kiyoshi | Zendy; IgashiraKamiyama Asako | Zendy; Kawamoto Tatsuya | Zendy; Konno Takumi | Zendy

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Metal‐Crossing between Thiolato‐Bridged Tetragold(I) and Tetrasilver(I) Metallorings

Author(s) -

Takino Yusuke,

Tsuge Kiyoshi,

IgashiraKamiyama Asako,

Kawamoto Tatsuya,

Konno Takumi

Publication year - 2011

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201100668

Subject(s) - metal , mixing (physics) , simple (philosophy) , crystallography , chemistry , materials science , physics , philosophy , quantum mechanics , organic chemistry , epistemology

The postman always rings twice : Thiolato‐bridged Au I 4 and Ag I 4 metallorings were selectively prepared by the reactions of benzothiazolines with Au I and Ag I , respectively. Simple 1:1 mixing of the Au I 4 and Ag I 4 metallorings led to the quick, exclusive formation of Au I 2 Ag I 2 metallorings from an unprecedented metal‐crossing reaction that produces a single kind of heterometallic rings from two kinds of homometallic rings.

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