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Sophisticated Crystal Transformation of a Coordination Polymer into Mesoporous Monocrystalline Ti–Fe‐Based Oxide with Room‐Temperature Ferromagnetic Behavior
Author(s) -
Hu Ming,
Belik Alexei A.,
Sukegawa Hiroaki,
Nemoto Yoshihiro,
Imura Masataka,
Yamauchi Yusuke
Publication year - 2011
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201100509
Subject(s) - monocrystalline silicon , materials science , ferromagnetism , oxide , mesoporous material , transformation (genetics) , coordination polymer , crystal structure , crystal (programming language) , polymer , chemical engineering , crystallography , condensed matter physics , metallurgy , chemistry , silicon , computer science , composite material , physics , organic chemistry , catalysis , engineering , biochemistry , programming language , gene
Have you been framed? Mesoporous monocrystalline K 0.8 Ti 4.3 Fe 3.7 O 16 cubes have been prepared by a sophisticated crystal transformation from a single‐crystalline titanium‐containing Prussian Blue analogue. This is a new strategy for the design of fully crystallized frameworks in mesoporous materials (see graphic).