Efficient Control for the Cationic Platinum(II)‐Catalyzed Concise Synthesis of Two Types of Fused Carbocycles with Angular Oxygen Functionality | Zendy

Kusama Hiroyuki | Zendy; Watanabe Eiichi | Zendy; Ishida Kento | Zendy; Iwasawa Nobuharu | Zendy

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Efficient Control for the Cationic Platinum(II)‐Catalyzed Concise Synthesis of Two Types of Fused Carbocycles with Angular Oxygen Functionality

Author(s) -

Kusama Hiroyuki,

Watanabe Eiichi,

Ishida Kento,

Iwasawa Nobuharu

Publication year - 2011

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201100460

Subject(s) - cycloaddition , chemistry , carbene , alkyl , moiety , ylide , ring (chemistry) , platinum , alkoxy group , organic chemistry , combinatorial chemistry , catalysis , medicinal chemistry

Double trouble : An efficient method for the preparation of two types of synthetically useful bicyclo[5.4.0]undecanes with an angular oxygen functionality was realized starting from easily available substrates; this method was based on the [3+2] cycloaddition reaction of the platinum‐containing carbonyl ylide (see scheme; R 1 =alkyl or alkoxy, R 2 =alkyl, R 3 =alkyl or vinyl).

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