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Hydrogen‐Bonding‐Induced Chirality Organization and Stabilization of Redox Species of Polyaniline‐Unit Molecules by Introduction of Amino Acid Pendant Groups
Author(s) -
Moriuchi Toshiyuki,
Ohmura Satoshi D.,
Morita Kenji,
Hirao Toshikazu
Publication year - 2011
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201100390
Subject(s) - chirality (physics) , moiety , redox , polyaniline , molecule , intramolecular force , hydrogen bond , chemistry , polymer chemistry , stereochemistry , combinatorial chemistry , organic chemistry , polymer , polymerization , physics , chiral symmetry breaking , quantum mechanics , nambu–jona lasinio model , quark
The chirality organization of polyaniline‐unit molecules was achieved by the introduction of amino acid pendant groups through intramolecular hydrogen bonding, which plays an important role in the stabilization of the chirality‐organized redox species. Another interesting feature of the synthesized polyaniline‐unit molecules is the luminescent switching properties based on the redox states of the phenylenediamine moiety.