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Kinetics Studies of the Enantioselective Hydroxymethylation of Silicon Enolates Using Aqueous Formaldehyde in the Presence of Sc(OTf) 3 and a Chiral 2,2′‐Bipyridine Ligand
Author(s) -
Mukherjee Chandan,
Kitanosono Taku,
Kobayashi Shū
Publication year - 2011
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201100353
Subject(s) - scandium , formaldehyde , kinetics , aqueous solution , chemistry , silicon , aqueous medium , enantioselective synthesis , ligand (biochemistry) , inorganic chemistry , catalysis , organic chemistry , biochemistry , physics , receptor , quantum mechanics
The kinetics of chiral scandium(III) ‐catalyzed hydroxymethylation of silicon enolates using aqueous formaldehyde have been investigated, and a reaction mechanism of this process in organic/aqueous medium is proposed.