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Double Hydroacylation Reactions of Acyclic and Cyclic α,β‐Unsaturated Aldehydes
Author(s) -
Cha KyungMi,
Lee Hyejeong,
Park JungWoo,
Lee Yura,
Jo EunAe,
Jun ChulHo
Publication year - 2011
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201100298
Subject(s) - hydroacylation , alkene , double bond , ketone , aldehyde , chemistry , enantiomer , organic chemistry , medicinal chemistry , catalysis
Double or quits? double hydroacylation reactions of acyclic and cyclic α,β‐unsaturated aldehydes with olefins afford ketone and diketone products, respectively. Enantiomers are formed whose absolute configurations are controlled by the order of alkene addition.