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Unexpected Formation of a trans‐syn ‐Fused Linear Triquinane from a Trimethylenemethane (TMM)‐Diyl‐Mediated [2+3] Cycloaddition Reaction .
Author(s) -
Kim WonYeob,
Kim Byung Gyu,
Kang Taek,
Lee HeeYoon
Publication year - 2011
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201100251
Subject(s) - trimethylenemethane , cycloaddition , intramolecular force , interpretation (philosophy) , substrate (aquarium) , chemistry , homonym (biology) , stereochemistry , computer science , philosophy , linguistics , organic chemistry , biology , catalysis , botany , ecology , genus
trans ‐Fused triquinane : Intramolecular‐trimethylenemethane‐mediated [2+3] cycloaddition reaction of a highly congested substrate proceeded stepwise to produce highly strained triquinane structures along with tricyclo[5.3.1.0 2, 6 ]undecanes.
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