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Gold(I)‐Catalyzed Cyclization of Alkynyl Hydrogen Phosphates
Author(s) -
Chary Bathoju Chandra,
Low Wee Suan,
Kim Sunggak,
Kim Hyunseok,
Lee Phil Ho
Publication year - 2011
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201100147
Subject(s) - intramolecular force , dig , catalysis , closure (psychology) , ring (chemistry) , combinatorial chemistry , chemistry , scheme (mathematics) , hydrogen , computer science , stereochemistry , organic chemistry , world wide web , mathematics , political science , mathematical analysis , law
Functionalization of alkynols : An efficient gold(I)‐catalyzed intramolecular hydrophosphoryloxylation of alkynyl hydrogen phosphates has been developed and provides structurally interesting cyclic vinyl phosphates through 6‐ endo‐dig , 6‐ exo‐dig , or 7‐ exo‐dig ring closure (see scheme).